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Thick Film Pastes for AlN Substrates: What They Are and Why They Matter

Thick film circuitry sits at the intersection of materials science and high-volume manufacturing.When electronic functionality must be built directly onto a ceramic substrate, thick film circuitry is often the most practical solution. Whether we need patterned conductors, precision resistors, or insulating layers, thick film pastes let us deposit functional materials by printing and convert them into durable films through firing.

Aluminum nitride (AlN) substrates deliver thermal performance that alumina cannot match. That matters in power electronics, RF hardware, and dense assemblies where heat drives reliability. 

The catch is that AlN is not a drop-in replacement for alumina in a thick-film process. Surface chemistry, thermal expansion behavior, and firing interactions differ enough that paste selection requires design-level attention rather than simple substitution.

Thick Film Pastes: A Printed Functional Layer

Thick film pastes are engineered suspensions used to build electrical functionality on a substrate. We print the paste (most commonly by screen printing), dry it to remove solvents, then fire it to densify the deposit, bond it to the ceramic, and make it electrically stable.

A typical paste formulation includes:

  • Functional particles that set the electrical role (for example, conductive metals for traces or resistive phases for resistor elements).
  • Glass frit and inorganic binders that support adhesion and film formation during firing.
  • An organic vehicle that controls viscosity, thixotropy, print definition, and drying behavior, then burns out during the firing profile.

Because the paste is a composite, performance is rarely determined by a single ingredient. Print resolution, fired microstructure, adhesion, and electrical stability come from how the system behaves as a whole through drying, burnout, sintering, and cool-down.

Why AlN Substrates Are Used

AlN is chosen when high thermal conductivity is required while maintaining electrical insulation. That combination is hard to obtain from metals, and it is not always adequate in conventional ceramics as heat flux rises.

In practical terms, AlN helps when:

  • Heat Must Leave the Device Quickly: Lower thermal resistance from die to baseplate can enable higher power density or reduce derating.
  • Electrical Isolation is Nonnegotiable: We can route signals or power across an insulating substrate without adding separate insulating layers that raise thermal resistance.
  • Thermal Cycling Reliability Matters: When the substrate effectively manages heat and reduces hotspots, the package often experiences less mechanical stress in solder joints, wire bonds, and interfaces.

Those benefits are real, but they only translate into hardware if the thick-film stack adheres, remains electrically stable, and withstands the module’s expected temperature profile.

What Makes AlN Different for Thick Film Processing

Surface Chemistry and Adhesion Behavior

AlN does not behave like alumina at the surface. Alumina is an oxide ceramic, and many thick-film glass systems were historically tuned around oxide bonding. 

AlN can form surface oxide under certain conditions, but the surface state can vary with substrate processing, storage, cleaning, and pre-firing steps. That variability can manifest as inconsistent wetting, weaker adhesion, or shifts in the fired microstructure at the interface.

For thick film, that means we treat the AlN surface as a controlled variable. Surface finish, cleaning protocol, and any intentional pre-oxidation or surface conditioning can materially change results.

Thermal Expansion Matching and Residual Stress

After firing, the film and substrate cool together. If thermal expansion mismatch is too large, the film can end up in tension or compression, which raises the chance of:

  • Microcracking in the film
  • Edge lifting at pads and corners
  • Delamination during thermal cycling
  • Resistance drift in resistor elements

The risk increases with thicker prints, large continuous conductor areas, and aggressive thermal gradients during operation or thermal cycling. Paste systems designed for AlN typically address these stresses through glass selection, particle loading, and fired-film compliance.

Firing Window and Interaction With the Substrate

Even when the peak temperature is similar to that used for alumina, burnout behavior and interfacial reactions can differ on AlN. If organics do not burn out cleanly, we can trap porosity or residue: 

  • If the glass flow is off-window, we can lose adhesion or print definition. 
  • If the firing profile is not aligned with the paste, we can get nonuniform sheet resistance across the panel.

With AlN, consistency comes from treating printing, drying, and firing as a single coupled process rather than independent steps.

Key Characteristics to Evaluate in Pastes for AlN

When we qualify Thick Film Pastes for AlN Substrates, we focus on a short list of measurable behaviors that connect directly to manufacturing yield and field reliability.

Adhesion and Interface Quality

Adhesion is not just a tape test result. We also look at:

  • Edge integrity after firing
  • Resistance to solder or bond process heat
  • Stability after thermal cycling and humidity exposure (as relevant to the application)
  • Signs of interfacial glass depletion or excessive reaction zones

If adhesion is marginal, it tends to fail first at corners, narrow traces, and pad edges where stress concentrates.

Electrical Stability Across Temperature

For conductors, we care about stable sheet resistance, consistent solderability or bondability, and minimal drift after process excursions. For resistor pastes, we care about:

  • Achievable tolerance after trimming (if used)
  • Repeatability lot-to-lot and panel-to-panel
  • Drift under thermal cycling and steady-state temperature exposure

For dielectric layers, we care about insulation resistance, breakdown behavior, and compatibility with adjacent conductors and resistors.

Processability and Print Definition

A paste that looks good on a datasheet can still fail the build if it does not print cleanly in your process window. We evaluate:

  • Print definition on the target mesh and emulsion thickness
  • Leveling behavior and edge sharpness
  • Drying sensitivity (skin formation, pinholes, slumping)
  • Reprint behavior in multilayer stacks

AlN programs often move fast from prototype to limited production. A paste system that prints reproducibly reduces rework and shortens process development.

CTE and Mechanical Compatibility

We match the paste system to AlN not only for peak performance, but for how the full stack behaves mechanically. That includes conductor-to-dielectric compatibility, resistor encapsulation compatibility, and how the fired films respond to the module’s operating temperature range.

Common Thick Film Paste Types for AlN

Conductive Pastes

Conductive pastes form traces, pads, and interconnect features. On AlN, the conductor system is often selected around downstream assembly requirements:

  • Solder attach versus wire bonding
  • Operating temperature and current density
  • Corrosion environment and protection strategy
  • Required conductivity and line width constraints

In practice, conductor selection also influences the rest of the stack. A conductor’s glass system and firing behavior can affect dielectric adhesion and resistor interactions.

Resistor Pastes

Resistor pastes are used for printed resistors, shunts, sensing elements, and integrated networks. Precision resistors on AlN matter when the module combines power handling with measurement or control.

In our lineup, the FK9600 and FK9900M systems are tailored for AlN substrates. These systems support printed resistor elements, where repeatability and stability are central to the design, and are commonly used when the circuit is close to heat sources or experiences rapid thermal transitions.

Via Filling and Encapsulation Pastes

Via filling paste exhibits very little sinter shrinkage in order to fill the via as completely as possible. This helps to establish contact between buried and surface mentalizations of multi-layer ceramics.  

Encapsulation paste is applied as a protective film onto thick-film resistors of the FK9600 and FK9900M resistor paste series, and onto its contacts. This prevents resistance drifts which could result from environmental factors, such as high air humidity or slight mechanical abrasion.

For AlN, we pay attention to:

  • Coverage without pinholes at the target print thickness
  • Adhesion to both AlN and fired conductor surfaces
  • Thermal cycling behavior in stacked structures
  • Whether the dielectric influences resistor values or stability when used as an overglaze/encapsulation layer

Where AlN Thick Film Circuits Are Used

The combination of printed functionality and high thermal conductivity makes AlN thick-film circuits relevant across three broad application areas:

Power Electronics Modules

AlN substrates are a common fit when power devices generate enough heat that substrate thermal conductivity becomes a limiter. Thick-film layers on AlN can support gate-drive routing, sensing networks, and interconnect features that sit close to the power stage. When modules cycle between load states, the thick-film stack must remain intact while the package undergoes repeated mechanical strain.

RF and Microwave Hardware

RF assemblies can benefit from AlN when heat dissipation and dimensional stability are critical. Thick film conductors are used for patterned features that must maintain geometry, continuity, and electrical consistency under temperature rise and environmental exposure. In certain builds, dielectric layers or protective coatings also contribute to long-term stability.

Sensors, Heaters, and High-Temperature Electronics

Printed resistors and conductors on AlN are used in sensor carriers, microheaters, and control elements, where the substrate serves as both a thermal path and a stable platform. In these applications, the resistor’s drift behavior and the conductor’s oxidation or corrosion resistance can drive system performance over time.

How We Support AlN Thick Film Builds

At AdValue Technology, we support AlN-based thick-film work in two ways: by stocking paste systems for AlN substrates and by helping teams align paste selection with the realities of their process flow.

As programs move from initial development to repeatable manufacturing, the technical requirements become more specific:

  • What is the AlN surface finish, and how is it prepared before printing?
  • What firing profile is available (conveyor versus box furnace, atmosphere constraints, peak temperature limits)?
  • Which layers must be co-fired, and which can be processed separately?
  • What assembly steps follow (soldering, bonding, trimming, encapsulation), and what thermal loads do they introduce?

We can support selection across conductor, resistor, and dielectric needs, including the FK9600 and FK9900M resistor systems for AlN, and help map the material choices to your intended firing and assembly path.

Move From Prototype to Production With AdValue Technology

Scaling a thick film process on AlN requires more than matching a datasheet to a substrate. It requires paste systems that behave consistently across panels, firing equipment, and production volumes — and technical support that understands where variability hides.

AdValue Technology stocks thick film pastes engineered for AlN substrates and works with teams to build repeatable processes. We help you identify the right materials, resolve process issues, and tighten tolerances as you scale.
Contact AdValue Technology to get the technical support you need to move forward.

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